Prof. Dolgikh group. Department of Chemistry, MSU (2024)

Inorganic Synthesis Laboratory, Inorganic chemistry division, Departmentof Chemistry, MSU

GROUPSTAFF

POSTGRADUATESTUDENTS

Contact V.A.Dolgikh

STUDENTS

GROUP ALUMNI

Dissertations & Diploma projects

PICTURES

Group Photo (approx end of 1992)

RESEARCH ACTIVITIES

Determination of the correlationsbetween composition, structure ferroelectric, ion-conducting and nonlinearoptic properties of crystals as the scientific base for design and synthesis ofinorganic compounds with required properties.

MAIN OBJECTSUNDER INVESTIGATION IN THE RECENT YEARS

Complex tellurites and selenites of bismuth and rare earth elements (REE), complexoxohalogenides and oxochalkogenides.

Large family of layered oxyhalogeniges of Bi(REE)-Te belonging to a new type was discovered and investigated.This family has a high percentage of compounds with noncentrosymmetricstructures. Among them the phases were found having high nonlinear opticparameters and unique combination of piezoelectric and pyroelectric parametersadvantageous for pyroelectric applications.
The correlations between the composition and the structure were determined forthe phases in this group.
With the help of planned heterovalent substitution ofBi or REE atoms in their fluorite-like oxofluorides, new anion-conductingphases with wide hom*ogenity regions were obtained.The correlation between nonstoichiometry andtransport characteristics of these solid solutions were determined.
Current interests include design, synthesis, crystallographic and SHGcharacterization of new layered and inorganic open framework phases.Research highlights

COLLABORATIONS

Prof. P. Lightfootin the School of Chemistry at the University ofSt Andrews, UK

Prof. Dr. rer. nat. Michael RuckAnorganische Chemie der TU Dresden, Germany

ProfessorAlain Tressaud Research Director at ICMCB-CNRS,University Bordeaux 1 (France)

CURRENT PROJECTS:

Russian ScienceFoundation 23-23-00205Synthesis of complex chalcogenite-chalcogenatesand chalcogenite-nitrates - substances with promisinglow-dimensional magnetic properties Supervisor P.S. Berdonosov

FINISHEDPROJECTS:

RFBR 14-03-00604Design and targeted synthesis of novel hybrid inorganic phases - saltinclusion solids Supervisor V.A. Dolgikh

RFBR11-03-00776 The synthesis concept and targeted synthesis of inorganic crystalphases with structures based on open framework 2011-2013 Supervisor V.A.Dolgikh
RFBR Royal Society UK 12-03-92604-KO-a A Crystal-chemicalApproach to New Frustrated Magnets 2012-2013 Supervisor V.A. Dolgikh
RFBR 12-03-00665 Directed synthesis of low dimensional d-metal complexselenite-halides as possible frustrated magnets 2012-2014 SupervisorP.S. Berdonosov

RFBR09-03-00799 Synthesis of the complex s-/d-metals,Bi/d-metalselenates(IV) halides and tellurates(IV) halides with noncentrosymmetricalstructures 2009-2011 Supervisor P.S. Berdonosov
RFBR 09-03-01064 Development and application of modular approach to design andsynthesis of complex inorganic layered perovskites 2009-2011 SupervisorD.O. Charkin

RFBR08-03-00548 The crystal chemistry approach to the design and targeted synthesisof new open-framework inorganic phases 2008-2010 Supervisor V.A. Dolgikh

PUBLICATIONS

USSR patent 1715712 V.A. Dolgikh, S.Yu. Stefanovich, B.A. Popovkin,L.N. Kholodkovskaya (Russian)

2024

Grigoriy Pashkov, Maria Markina, Konstantin Lyssenko, Peter Berdonosov, Synthesis, Crystal Structure, and Thermodynamic Properties of Two New Selenate Chlorides: M₂Cu(SeO₄)Cl₂ with M = K and Rb // Materials Chemistry and Physics, Volume 319, 1 June 2024, 129367https://doi.org/10.1016/j.matchemphys.2024.129367

M.M. Markina, P.S. Berdonosov, T.M. Vasilchikova, K.V. Zakharov, A.F. Murtazoev, V.A. Dolgikh, A.V. Moskin, V.N. Glazkov, A.I. Smirnov, A.N. Vasiliev Static and resonant properties of decorated square kagom'e lattice KCu₇(TeO₄)(SO₄)₅Cl // Materials Chemistry and Physics, Volume 319, 1 June 2024, 129348https://doi.org/10.1016/j.matchemphys.2024.129348

Oksana Grigoreva, Tatiana Shatalova, Alexey N. Kuznetsov, Peter S Berdonosov, Sergey Stefanovich, Konstantin Lyssenko and Valery Dolgikh New iodate fluoride Rb₂Ce(IO₃)₅F with nonlinear optical properties // Dalton Trans., 2024, Accepted https://doi.org/10.1039/D4DT00431K

Ya.V. Rebrov, V.N. Glazkov, A.F.Murtazoev, V.A. Dolgikh, P.S. Berdonosov High-frequencydielectric anomalies in a highly frustrated square kagomélattice nabokoite family compounds ACu₇(TeO₄)(SO₄)₅Cl(A=Na, K, Rb, Cs)// Journal ofMagnetism and Magnetic Materials, 2024, 171786, https://doi.org/10.1016/j.jmmm.2024.171786

2023

Alisher F Murtazoev, Peter S Berdonosov, Konstantin Lyssenko, ValeryDolgikh, Mikhael Geidorf, Olga S. Volkova, Hyun-Joo Koo, Mike Whangboand Alexander Vasiliev Cascade of Magnetic Phase Transitions and1/3-Magnetization Plateau in Selenite-Selenate Co₃(SeO₃)(SeO₄)(OH)2with Layers of a Kagomé-like Co2+ IonArrangement: Importance of Identifying a Correct Spin Lattice // Dalton Trans., 2023,52, 9664-9672 https://doi.org/10.1039/D3DT01620J

Alisher F Murtazoev,Peter S Berdonosov, Konstantin Lyssenko, ValeryDolgikh, Zlata Victorovna Pchelkina, KonstantinZakharov, Mikhael Geidorf,Tatyana M. Vasilchikova, Olga S. Volkova andAlexander Vasiliev Anhydrous coppertellurite-disulfate Cu₃TeO₃(SO₄)₂featuring coexistence of spin singlets and long-range antiferromagnetic order// Dalton Trans., 2023,52,9247-9253 https://doi.org/10.1039/D3DT01290E

Alisher F Murtazoev,Konstantin A Lyssenko,Maria M. Markina,Valery A. Dolgikh,Alexander N. Vasiliev,Peter Berdonosov New Nabokoite-Like Phases ACu₇TeO₄(SO₄)₅Cl(A = Na, K, Rb, Cs) with Decorated and Distorted Square Kagome Lattices // ChemPhysChem 2023, e202300111. https://doi.org/10.1002/cphc.202300111

Olga S. Volkova,Peter S. Berdonosov, Irina K. Shamova, Badiur Rahaman, Asif Iqbal, Tanusri Saha-Dasgupta,Alexander N. Vasiliev, Thermal and magnetic properties of Cu₄O(SeO₃)₃composed by ferrimagnetic O₂Cu₆ units of edge-sharing OCu₄tetrahedra // J. Alloys and Comp. 956 (2023) 170346, https://doi.org/10.1016/j.jallcom.2023.170346

A. F.Murtazoev, P. S. Berdonosov, S. M. Aksenov, A. N. Kuznetsov, V. A. Dolgikh, Y.V. Nelyubina and S. Merlino Polytypism of Ln(SeO₃)(HSeO₃)·2H₂O compounds: synthesis and crystal structure ofthe first monoclinic modification of Nd(SeO₃)(HSeO₃)·2H₂O, DFTcalculations and order/disorder description // Acta Cryst.(2023). B79 https://doi.org/10.1107/S2052520622012227

Sergei Klimin, Peter Berdonosov, Elena Kuznetsova MagneticOrdering and Interplay between the Magnetic and Charge Subsystems in New Francisite-Analog Cu₃Dy(SeO₃)₂O₂Clas Studied by the Spectroscopy of Kramers Doublets //Phys. Status Solidi RRL 2023, 2200460 https://doi.org/10.1002/pssr.202200460

Maria Markina, Tatyana Vasilchikova, Elena Kuznetsova, Peter Berdonosov, AndreyOlenev, Seung Hwan Chung, Hyun-Joo Koo, Myung-Hwan Whangbo,and Alexander Vasiliev Preparation and Characterization of FrancisiteSolid Solutions Cu3Bi(Se_1-xTexO₃)₂O₂Br(x = 0-1): Possibility for Francisites as // Chem.Mater. 2023, 35, 511-520 Starting Materials for Oxide van der WaalsFerromagnets DOI: https://doi.org/10.1021/acs.chemmater.2c02865

Dmitri O. Charkin, VasiliYu. Grishaev, Artem S. Borisov, Pavel A. Chachin, Evgeni V. Nazarchuk, Oleg I. SiidraA nonpolar bond to hydrogen vs. lone pair: Incorporation of HPO₃^2-and SeEO₃^2- into a lead perrhenate framework // J. of Solid State Chemistry 318 (2023) 123706 DOI: https://doi.org/10.1016/j.jssc.2022.123706

2022

Dmitri O. Charkin, ValeriA. Dolgikh, Timofey A. Omelchenko, Yulia A. Vaitieva,Sergey N. Volkov, Dina V. Deyneko and Sergey M.Aksenov Symmetry Analysis of the Complex Polytypismof Layered Rare-Earth Tellurites and Related Selenites:The Case of Introducing Transition Metals. // Symmetry 2022, 14, 2087. DOI: https://doi.org/10.3390/sym14102087

Markina M, Zakharov K, Ovchenkov Y, Pashkov G, LyssenkoK, Berdonosov P, Pchelkina Z, Vasiliev A. Quasi-One-Dimensional Linarite-Type PbCu(SeO4)(OH)2with Competing Nearest-Neighbor and Next-Nearest-Neighbor Intrachain ExchangeInteractions. Materials. 2022; 15(21):7860. DOI: https://doi.org/10.3390/ma15217860

A. N. Vasiliev, P.S.Berdonosov, E.S. Kozlyakova, O. V. Maximova, A. F. Murtazoev, V. A. Dolgikh, K.A. Lyssenko, Z. V. Pchelkina, D. I. Gorbunov, S. H.Chung, H.-J. Koof, M.-H. WhangboObservation of a 1/3 magnetization plateau in Pb₂Cu₁₀O₄(SeO₃)₄Cl₇arising from (Cu²⁺)₇ clusters of corner-sharing (Cu²⁺)₄tetrahedra // Dalton Trans., 2022,51, 15017-15021 DOI: DOI:10.1039/D2DT02316D

S. Spachmann,P. Berdonosov, M. Markina, A. Vasiliev & R. Klingeler Linear magnetoelasticcoupling and magnetic phase diagrams of the buckled kagomeantiferromagnet Cu₃Bi(SeO₃)₂O₂Cl// Scientific Reports (2022) 12:7383 DOI: https://doi.org/10.1038/s41598-022-11368-5

Dmitri O. Charkin, SergeyN. Volkov, Valeri A. Dolgikh, Sergey M. Aksenov Potassium rare-earth telluritechlorides: A new branch from the old root // Solid State Sciences, 2022, 1,39-48 DOI 10.1016/j.solidstatesciences.2022.106895

Alisher F.Murtazoev, Sergey G. Dorofeev,Alexey O.Gudovannyy, Konstantin A.Lyssenko,Valery A.Dolgikh, Peter S.BerdonosovNew europium selenate (Vi) tetrahydrate: Crystal structure and opticalproperties // Journal of Solid State Chemistry Volume 311, July 2022, 123090DOI 10.1016/j.jssc.2022.123090

Климин С.А., КузнецоваЕ.С., Бердоносов П.С. Штарковские уровнииона SmБ³⁺ в низкоразмерноммагнетике Cu₃Sm(SeO₃)₂O₂Cl// Оптика и спектроскопия,2022, 1, 39-48 DOI 10.21883/OS.2022.01.51888.37-21

Новикова Н.Н., Яковлев В.А., Кузнецова Е.С., Бердоносов П.С. КлиминС.А. Химическое сжатие, структурная нестабильность и ИК-активные фононы в рядуредкоземельных аналогов францисита Cu₃RE(SeO₃)₂O₂Cl // Оптика испектроскопия 130(2022) 49-58 DOI: 10.21883/OS.2022.01.51889.22-21

2021

Kazuhiro Nawa, MaximAvdeev, Peter Berdonosov, Alexey Sobolev, Igor Presniakov,Alena Aslandukova, Ekaterina Kozlyakova, AlexanderVasiliev, Igor Shchetinin, Taku J. Sato Magnetic structure study of thesawtooth chain antiferromagnet Fe₂Se₂O₇ // SciRep 11, 24049 (2021). DOI:10.1038/s41598-021-03058-5a>

S. A. Klimin,P. S. Berdonosov, E. S. Kuznetsova Quasi-doublets of non-KramersHo3+ ion and magnetic ordering of holmium francisite-analogCu3Ho(SeO₃)₂O₂Cl //Low Temperature Physics 47(12), 1022–1029 (2021) DOI: 10.1063/10.0007075

K. Denisova, P. Lemmens,D. Wulferding, P. Berdonosov, V. Dolgikh, A.Murtazoev, E. Kozlyakova, O. Maximova, A. Vasiliev, I. Shchetinin, F. Dolgushin, A. Iqbal, B. Rahaman, T. Saha-Dasgupta,Cu₉O₂(SeO₃)₄Cl₆ revisited:crystal structure, Raman scattering and first-principles calculations //Journal of Alloys and Compounds, Volume 894, 2022, 162291, DOI:10.1016/j.jallcom.2021.162291

Alisher F. Murtazoev,Peter S. Berdonosov, Victor A. Tafeenko, Valery A.Dolgikh, Igor L. Danilovich, Zlata V. Pchelkina, Alexander N. Vasiliev Cadmiumcopper selenite chloride, CdCu₂(SeO₃)₂Cl₂,an insulating spin gap system // Journal of Solid StateChemistry, Volume 303, 2021, 122518, DOI: 10.1016/j.jssc.2021.122518

Kozlyakova, E.S., Moskin,A.V., Berdonosov, P.S., V. V. Gapontsev, S. V.Streltsov, M. Uhlarz, S. Spachmann,A. ElGhandour, R. Klingeler, A. N. Vasiliev Quasi-1DXY antiferromagnet Sr₂Ni(SeO₃)₂Cl₂at Sakai-Takahashi phase diagram. // Sci Rep 11, 15002 (2021). DOI: 10.1038/s41598-021-94390-3

S. A. Klimin,P. S. Berdonosov, E. S. Kuznetsova Optical Spectroscopy of KramersDoublets of an Er3+ Ion in a Two-Dimensional Frustrated Magnetic Cu₃Er(SeO₃)₂O₂Cl // Optics andSpectroscopy, 2021, Vol. 129, No. 1, pp. 47–50 DOI: 10.1134/S0030400X21010094

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Last updated 14.12.2020